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El Niño–Southern Oscillation (ENSO) is known to have teleconnections to atmospheric circulations and weather patterns around the world. Previous studies have examined connections between ENSO and rainfall in tropical South America, but little work has been done connecting ENSO phases with convection in subtropical South America. The Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR) has provided novel observations of convection in this region, including that convection in the lee of the Andes Mountains is among the deepest and most intense in the world with frequent upscale growth into mesoscale convective systems. A 16-yr dataset from the TRMM PR is used to analyze deep and wide convection in combination with ERA-Interim reanalysis storm composites. Results from the study show that deep and wide convection occurs in all phases of ENSO, with only some modest variations in frequency between ENSO phases. However, the most statistically significant differences between ENSO phases occur in the three-dimensional storm structure. Deep and wide convection during El Niño tends to be taller and contain stronger convection, while La Niña storms contain stronger stratiform echoes. The synoptic and thermodynamic conditions supporting the deeper storms during El Niño is related to increased convective available potential energy, a strengthening of the South American low-level jet (SALLJ), and a stronger upper-level jet stream, often with the equatorward-entrance region of the jet stream directly over the convective storm locations. These enhanced synoptic and thermodynamic conditions provide insight into how the structure of some of the most intense convection on Earth varies with phases of ENSO.